pH Electrodes Designed and Manufactured by Hanna The formula for obtaining the rH value is as follows: rH= mV -2 pH 0.0992 (273.15 + Tc) In this equation, where T is the temperature (°C) of the sample, mV is the ORP (mV) reading, and pH is the pH value of the sample. The rH scale is not used in the instruments available on the market. A direct mV reading from the electrode is preferred, within the ±2000 mV range, without compensation/correlation with the pH/ temperature value. ORP Applications ORP measurements are based on the potential difference measured between the platinum or gold electrode and a reference electrode. The identical reference system utilized for the pH electrode (Ag/AgCl) is also used for redox measurements. Redox electrodes are used to monitor many chemical processes particularly those involving reversible reactions. Common applications include the following: Industrial Wastewater Treatment The redox systems used in water treatment are the reduction of chromates and oxidation of cyanides. Waste hexavalent chromium is reduced to trivalent chromium by the addition of sodium bisulfite or sulphur dioxide. In the case of cyanide, chlorine or sodium hypochlorite is used to oxidize the cyanide, followed by the hydrolysis of cyanate to ammonia and carbon dioxide. Water Sanitation ORP measurements are being increasingly used as an effective measure of the sanitizing activity in pool, spa, and potable water. The kill time of E. coli bacteria in water depends on the ORP value. ORP is a reliable indicator of bacteriological water quality. Water having an ORP value equal to or higher than 650 mV are well within accepted sanitization levels for pool and spa waters. Electrode Feature Guide: A Quick Glance CAL Check™ System When used in tandem with a Hanna CAL Check meter, our CAL Check equipped electrodes allow users to be informed if they have performed a proper calibration. In the event of a dirty or broken electrode or contaminated buffer solution, the system alerts the user to either check the electrode, replace the buffer solution, or both. The system also reminds users when the instrument should be recalibrated. Smart Electrodes With models that feature our SMART circuitry, an exclusive microchip embedded inside the electrode retains the calibration data and assigns an identity code to the host unit. As soon as the electrode is connected to a pH meter in the SMART series, it is recognized and its characteristics retrieved. The meter then uses the accessed calibration data as a reference for future measurements. Once each SMART electrode is calibrated, these electrodes can be used in succession without requiring new calibration. Hanna’s SMART electrodes help eliminate errors and save time when working with more than one electrode. Pre-amplified Electrodes Pre-amplifiers are encapsulated in many of Hanna’s pH electrodes. The pre-amplifier converts the high impedance signal from the pH glass to a low impedance signal; this allows the user to use long runs of sensor cable with ordinary connectors without noise or voltage drops that result in erroneous measurements. Clogging Prevention System (CPS™) Conventional pH electrodes use ceramic junctions that may clog quickly when used in biological samples, such as wine or must. When the junction is blocked, the entire electrode will not function properly. Electrodes that feature CPS technology utilize a ground glass/ PE sleeve junction which controls a steady, predictable flow of fill solution, thus keeping the junction open. The hydrophobic property of PE sleeve repels wetness and coatings. Sensor Check™ for edge® Meters When used with Hanna’s electrodes equipped with a matching pin, edge constantly checks the impedance of the pH measuring electrode to notify the user, in real-time, in the event of glass breakage. During calibration, Sensor Check also verifies the state of the junction. Titanium Casings Our electrodes that feature titanium bodies offer durability and shielding that is required in many industrial applications. 2 pH 2.133 www.hannainst.com | electrodes
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